Michael Medvedev
- Associate Professor:Joint Department of Organic Chemistry with the RAS Zelinsky Institute of Organic Chemistry
- Michael Medvedev has been at HSE University since 2019.
Education and Degrees
- 2018
Candidate of Sciences* (PhD)
Lomonosov Moscow State University - 2018
Doctoral programme in Chemistry
Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences - 2016
Degree in Fundamental and Applied Chemistry
Mendeleev University of Chemical Technology of Russia
* Candidate of Sciences
According to the International Standard Classification of Education (ISCED) 2011, Candidate of Sciences belongs to ISCED level 8 - "doctoral or equivalent", together with PhD, DPhil, D.Lit, D.Sc, LL.D, Doctorate or similar. Candidate of Sciences allows its holders to reach the level of the Associate Professor.
According to the International Standard Classification of Education (ISCED) 2011, Candidate of Sciences belongs to ISCED level 8 - "doctoral or equivalent", together with PhD, DPhil, D.Lit, D.Sc, LL.D, Doctorate or similar. Candidate of Sciences allows its holders to reach the level of the Associate Professor.
Courses (2023/2024)
- Information Technology in Chemistry (Bachelor’s programme; Faculty of Chemistry; 1 year, 1-3 module)Rus
- Past Courses
Courses (2022/2023)
- Chemical Information Search (Bachelor’s programme; Faculty of Chemistry; 2 year, 4 module)Rus
- Information Technology in Chemistry (Bachelor’s programme; Faculty of Chemistry; 1 year, 1, 2, 4 module)Rus
Courses (2021/2022)
- Digital Literacy. Information Technology in Chemistry (Bachelor’s programme; Faculty of Chemistry; 1 year, 1-4 module)Rus
- Machine Search of Information in Chemistry (Bachelor’s programme; Faculty of Chemistry; 2 year, 3 module)Rus
- Quantum Chemistry (Bachelor’s programme; Faculty of Chemistry; 3 year, 2, 3 module)Rus
Courses (2020/2021)
Information Technology. Data Culture (Bachelor’s programme; Faculty of Chemistry; 1 year, 1-4 module)Rus
Courses (2019/2020)
Information Technology in Chemistry (Bachelor’s programme; Faculty of Chemistry; 1 year, 1-4 module)Rus
20241
Article Медведев М. Г., Миракбаров М. Х., Зарипов Д. У., Вацадзе С. З., Медведько А. В., Миняев М. Е., Хрусталёв В. Н., Алабугин И. В. Не все углерод-углеродные связи одинаковы: аномерный эффект sp-гибридного атома углерода // Известия Академии наук. Серия химическая. 2024. № 2. С. 363-372. (in press)
20231
Article Yaremenko I. A., Belyakova Y. Y., Radulov P. S., Michael G. Medvedev, Krivoshchapov N. V., Alabugin I. V., Terent’ev A. O. Two-Component versus Three-Component Condensations in the Race between Hydrazide, Triketone, and Hydrogen Peroxide-How do All Six Reactive Centers Cooperate to Incorporate the Most Diverse Set of Heteroatomic Bridges in a Tricyclic Frame? // Journal of Organic Chemistry. 2023. Vol. 88. No. 19. P. 13782-13795. doi
20223
- Article Gerasimov I. S., Losev T. V., Evgeny Yu. Epifanov, Rudenko I., Bushmarinov I. S., Ryabov A. A., Zhilyaev P. A., Medvedev M. Comment on “Pushing the frontiers of density functionals by solving the fractional electron problem” // Science. 2022. Vol. 377. No. 6606. Article eabq3385. doi
- Article Medvedev M., Stroganov O., Dmitrienko A. O., Panova M., Lisov A., Svitanko I., Novikov F. N., Chilov G. G. Reducing false-positive rates in virtual screening via cancellation of systematic errors in the scoring function // Mendeleev Communications. 2022. Vol. 32. No. 6. P. 735-738. doi
- Article Rinat F. Salikov, Belyy A. Y., Trainov K. P., Velmiskina J. A., Michael G. Medvedev, Korshunov V. M., Taydakov I. V., Platonov D. N., Tomilov Y. V. Superphotoacidic properties and pH-switched Stokes shifts in electron-deficient 5-hydroxyisoquinolone derivatives // Journal of Photochemistry and Photobiology A: Chemistry. 2022. Vol. 427. Article 113808. doi
20213
- Article Kuznetsova S., Gorodishch I., Gak A., Zherebtsova V., Gerasimov I., Michael G. Medvedev, Kitaeva D., Ekaterina A. Khakina, North M., Belokon Y. Chiral titanium(IV) and vanadium(V) salen complexes as catalysts for carbon dioxide and epoxide coupling reactions // Tetrahedron. 2021. Vol. 82. Article 131929. doi
- Article Kotov V.Yu., Buikin P.A., Ilyukhin A., Korlyukov A., Ananyev I.V., Gavrikov A., Medvedev M.G. Hybrid iodobismuthates code: adapting the geometry of Bi polyhedra to weak interactions // Mendeleev Communications. 2021. Vol. 31. P. 166-169. doi
- Article Omelchuk O. A., Malyshev V. I., Medvedev M., Lysenkova L. N., Belov N. M., Dezhenkova L. G., Grammatikova N. E., Scherbakov A. M., Shchekotikhin A. E. Stereochemistries and Biological Properties of Oligomycin A Diels–Alder Adducts // Journal of Organic Chemistry. 2021. Vol. 86. No. 12. P. 7975-7986. doi
20203
- Article Balagurova E. V., Dolgushin F. M., Medvedev M., Kononova E. G., Godovikov I. A., Smol′yakov A. F., Chizhevsky I. T. Manganа- and rhena-copper carboranes based on the medium-size non-icosahedral 5,6-dicarba-nido-decaborane // Journal of Organometallic Chemistry. 2020. Vol. 911. Article 121141. doi
- Article Telegina L. N., Strelkova T. V., Ezernitskaya M. G., Medvedev M., Kelbysheva E. S. Synthesis and photochemical study of tricarbonyl and dicarbonyl derivatives of 3-cymantrenylalkylisothioureas // Journal of Organometallic Chemistry. 2020. Vol. 926. Article 121465. doi
- Article Stroganov O. V., Novikov, FN, Medvedev, MG, Dmitrienko A. O., Svitanko, IV. The role of human in the loop: lessons from D3R challenge 4 // Journal of Computer-Aided Molecular Design. 2020. Vol. 34. No. 2. P. 121-130. doi
20197
- Article Medvedev M., Kuznetsov N. Y., Malishev V. I., Bubnov Y. N. DFT and experimental study of triallylborane-mediated isomerization of a-allylated azaheterocycles // Mendeleev Communications. 2019. Vol. 29. P. 190-193. doi
- Article Larionov V. A., Yashkina L. V., Medvedev M., Smol'yakov A. F., Peregudov A. S., Pavlov A. A., Eremin D. B., Savel'yeva T. F., Maleev V. I., Belokon Y. N. Henry Reaction Revisited. Crucial Role of Water in an Asymmetric Henry Reaction Catalyzed by Chiral NNO-Type Copper(II) Complexes // Inorganic Chemistry. 2019. Vol. 58. No. 16. P. 11051-11065. doi
- Article Ivanov S. M., Dmitrienko A. O., Medvedev M., Mironovich L. M. Metalated azolo[1,2,4]triazines. II. Generation, C(4)-substituent dependent stability and electrophile trapping of 7-lithiopyrazolo[5,1-c][1,2,4]triazines // Journal of Organometallic Chemistry. 2019. Vol. 896. P. 168-182. doi
- Article Medvedev M., Salikov R. F., Trainov K. P., Davydov D. N., Lee S., Gerasimov I. S., Levina A. A., Belyy A. Y., Tomilov Y. V. Synthesis and TD-DFT investigation of arylhydrazonocyclopentadiene dyes // Dyes and Pigments. 2019. Vol. 161. P. 500-509. doi
- Article Salikov R., Trainov K., Platonov D., Davydov D., Lee S., Gerasimov I., Medvedev M., Levina A., Belyy A., Tomilov Y. Synthesis and TD-DFT investigation of arylhydrazonocyclopentadiene dyes // Dyes and Pigments. 2019. Vol. 161. P. 500-509. doi
- Article Medvedev M., Belyy A. Y., Levina A. A., Platonov D. N., Salikov R. F., Tomilov Y. V. Synthesis of Diazanorcaradienes and 1,2-Diazepines via the Tandem [4+2]-Cycloaddition/Retro-[4+2]-Cycloaddition Reaction between Methoxycarbonylcyclopropenes and Dimethoxycarbonyltetrazine // European Journal of Organic Chemistry. 2019. Vol. 2019. No. 26. P. 4133-4138. doi
- Article Medvedev M., Larionov V. A., Savel'yeva T. F., Stoletova N. V., Smol'yakov A. F., Gugkaeva Z. T., Cruchter T., Maleev V. I. The Selective N-Functionalization of Indoles via aza-Michael Addition in the Ligand Sphere of a Chiral Nickel(II) Complex: Asymmetric Synthesis of (S)-1H-Indole-Alanine Derivatives // European Journal of Organic Chemistry. 2019. Vol. 2019. No. 22. P. 3699-3703. doi
20182
- Article Medvedev M., Marjewski A. A., Gerasimov I. S., Panova M. V., Perdew J. P., Lyssenko K. A., Dmitrienko A. O. Interplay between test sets and statistical procedures in ranking DFT methods: The case of electron density studies // Mendeleev Communications. 2018. Vol. 28. No. 3. P. 225-235. doi
- Article Akchurin I. O., Yakhutina A. I., Bochkov A. Y., Solovjova N. P., Medvedev M., Traven V. F. Novel push-pull fluorescent dyes – 7-(diethylamino)furo- and thieno[3,2-c]coumarins derivatives: structure, electronic spectra and TD-DFT study // Journal of Molecular Structure. 2018. Vol. 1160. P. 215-221. doi
20176
- Article Heindl C., Peresypkina E., Virovets A. V., Bushmarinov I. S., Medvedev M., Kramer B., Dittrich B., Scheer M. An Icosidodecahedral Supramolecule Based on Pentaphosphaferrocene: From a Disordered Average Structure to Individual Isomers // Angewandte Chemie - International Edition. 2017. Vol. 56. No. 43. P. 13237-13243. doi
- Article Cruchter T., Medvedev M., Shen X., Mietke T., Harms K., Marsch M., Meggers E. Asymmetric Nucleophilic Catalysis with an Octahedral Chiral-at-Metal Iridium(III) Complex // ACS Catalysis. 2017. Vol. 7. No. 8. P. 5151-5162. doi
- Article Medvedev M., Bushmarinov I. S., Sun J., Perdew J. P., Lyssenko K. A. Density functional theory is straying from the path toward the exact functional // Science. 2017. Vol. 355. No. 6320. P. 49-52. doi
- Article Traven V. F., Pozharskaya N. A., Solovjova N. P., Novikov R. A., Medvedev M., Chernyshev V. V., Dolotov S. M., Ivanov I. V. One-pot synthesis of new acid photogenerators for Rhodamine laser dyes fluorescence activation // Dyes and Pigments. 2017. Vol. 136. P. 612-618. doi
- Article Medvedev M., Zeifman A. A., Novikov F. N., Bushmarinov I. S., Stroganov O. V., Titov I. Y., Chilov G. G., Svitanko I. Quantifying Possible Routes for SpnF-Catalyzed Formal Diels–Alder Cycloaddition // Journal of the american chemical society. 2017. Vol. 139. No. 11. P. 3942-3945. doi
- Article Salikov R. F., Trainov K. P., Levina A. A., Belousova I. K., Medvedev M., Tomilov Y. V. Synthesis of Branched Tryptamines via the Domino Cloke–Stevens/Grandberg Rearrangement // Journal of Organic Chemistry. 2017. Vol. 82. No. 1. P. 790-795. doi
Employment history
| 2018-now | Research Fellow, Laboratory of Molecular Modeling, N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences |
| 2016-now | Research Fellow, Laboratory of X-Ray Diffraction, A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Russia |
Scientists Doubt that DeepMind’s AI Is as Good for Fractional-Charge Systems as it Seems
In their paper published in Science in 2021, a DeepMind team showed how neural networks can be used to describe electron interactions in chemical systems more accurately than existing methods. A team of researchers from Skoltech, the Zelinsky Institute of Organic Chemistry, HSE University, Yandex, and Kyungpook National University show in their comment in Science that DeepMind AI’s ability to generalise the behaviour of such systems does not follow from the published results and requires revisiting, the Skoltech website says.